"maybe I could just go ahead and drop both at one time to be copied."
Using Finder, how do you drop two camera files at one time to be copied to two separate destination drives?
Maybe you mean two consecutive drag/drop operations to two different destination drives, which will run concurrently.
If you have two different camera cards, you can do two separate Finder drag/drop operations to copy those concurrently to two different destination drives. There is nothing wrong with that. It will be faster.
OTOH if you have two files on a single camera card, the card I/O bandwidth will probably be maxed out on the first copy, so doing two won't make it much faster.
If you have a single destination drive and two camera cards, if the cards are SDXC V90 and if the destination drive is SSD, it is likely faster to concurrently copy the camera files to the single SSD. Reason: a typical Mac SSD or external SSD is 2x faster than a typical v90 SDXC card, so it can handle 2 incoming copies from the slower SDXC cards.
But if the destination is a mechanical drive, doing two concurrent copies to that destination will cause "seek contention" and can be slower than copying the two files sequentially.